The 3D porous metal-organic framework constructed by Cd(II) with 2-methylimidazole-4,5-dicarboxylic acid
Affiliation of Author(s):
化学与化工学院
Journal:
Monatshefte für Chemie / Chemical Monthly
Key Words:
中文关键字:配合物;3D 有机金属网状结构;X射线结构确定;荧光,英文关键字:Complex; 3D metal-organic framework; X-ray structu
Abstract:
A 3D metal-organic framework, [C6H3CdN2O4] center dot NH4, was synthesized solvothermally and structurally characterized by single-crystal X-ray structure determination. This compound crystallizes in the tetragonal system with the space group P42/nmc. The crystal structure presents a 3D framework and open channels, exhibiting guest-coordination sites at channel walls and strong fluorescent emission.