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1.1998-2001: Graduated from Northwest University of China with a master's degree; 2.2004-2010: Graduated from Xi 'an University of Architecture and Technology with Doctor's degree. Work Experience: 1.1991-1998: Former Tenth Research Institute of the Ministry of Posts and Telecommunications; 2.2011-2012: Visiting Scholar, Ohio State University, USA; 3. 2001-present: Served as a chemistry teacher of Xi 'an University of Architecture and Technology.
何盈盈
Associate Professor
Paper Publications
Interaction Mechanism of Anthracene with Benzoic Acid and its Derivatives
Release time:2024-08-09 Hits:
Affiliation of Author(s):
化学与化工学院
Journal:
Chiese Journal of chemistry
Key Words:
中文关键字:苯甲酸衍生物;蒽;π-π电子给体受体作用;π-H氢键,英文关键字:benzoic acid derivative;anthracene;π-π electron do
Abstract:
Interaction mechanism of anthracene, one of the typical polycyclic aromatic hydrocarbons, with benzoic acid and its hydroxyl-substituted derivatives, o-hydroxylbenzoic acid and p-hydroxylbenzoic acid, were studied using FTIR, UV and fluorescence spectra. The experiments confirmed that there was a specific and oriented interaction between anthracene and the aromatic carboxylic acids, and the bonding mode depended on both the chemical structure of reactants and acidity of solution. The π-H hydrogen bond played a main role in the interaction between anthracene and the aromatic carboxylic proton of benzoic acid or o-hydroxylbenzoic acid when pH lower than pKa, and the π-π electron donor-acceptor (EDA) interaction increasingly became the main binding mode when pH larger than pKa. The decrease of interaction intensity of benzoic acid was observed by introducing hydroxyl at its ortho position. The special D-π-A structure of p-hydroxylbenzoic acid made it easy to form the planar multi-molecule congeries that could interact with anthracene, so the interaction between anthracene and p-hydroxylbenzoic acid always followed the π-π EDA model no matter the solution acidity. For p-hydroxylbenzoic acid, the π-π interaction mode remained unchanged when pH increased from 2.0 to 10.0, and the binding intensity was higher than that between benzoic acid and anthracene because of the formation of the multi-molecule congeries.
Note:
何盈盈
Co-author:
范晓远,赵波
First Author:
金鹏康,王晓昌,heyingying
Indexed by:
Journal paper
Volume:
卷:26
Issue:
期:8
Page Number:
页:1373
Translation or Not:
no
Date of Publication:
2008-08-01

Pre One:Dual electrochemical catalysis of Bi2Mo3O12/Ti cathode for hydrogen peroxide production in electro-Fenton system,