Paper Publications

Improvement of ZnO nanorod-based dye-sensitized solar cell efficiency by Al doping

Release time:2024-08-09
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Affiliation of Author(s):
材料科学与工程学院
Journal:
Journal of Physics and Chemistry of Solids
Key Words:
中文关键字:电性能,英文关键字:Nanostructures;Semiconductors;Chemical synthesis;E
Abstract:
The current study investigates the performance of dye-sensitized solar cells (DSSCs) based on Al-doped and undoped ZnO nanorod arrays synthesized by a simple hydrothermal method. Current density– voltage (J–V) characterizations indicate that Al-doping in ZnO crystal structure can significantly improve current densities and the energy conversion efficiency (Z) of ZnO nanorod-based DSSCs. The maximum Z, 1.34%, was achieved in DSSC when Al-doped ZnO nanorod arrays were grown in 0.04 M zinc acetate dihydrate solution with 5 mMaluminum nitrate nonahydrate. This result represents a large increase of Z in Al-doped ZnO nanorod-based DSSCs as compared to undoped (0.05%). The improved DSSC photovoltaic performance can be attributed to two main factors: (1) increased light harvesting efficiency due to a large amount of N719 adsorbed on the large surface area of Al-doped ZnO nanorod arrays, and (2) increased electrical conductivity due to A13+ ion doped into the ZnO lattice at the divalent Zn2+ site, allowing electrons to move easily into the Al-doped ZnO conduction band.
Note:
云斯宁
Co-author:
JuneyoungLee,JooyoungChung,SangwooLim
First Author:
yunsining
Indexed by:
Journal paper
Volume:
卷:
Issue:
期:71
Page Number:
页:1724-1731
Translation or Not:
no
Date of Publication:
2010-08-01