所属单位：材料科学与工程学院

发表刊物：Journal of Alloys and Compounds

关键字：中文关键字：铁电，X衍射，介电响应，英文关键字：ferroelectric；X-ray diffraction；dielectric respons

摘要：The structural, dielectric and ferroelectric properties of chemical modified (BCT-NBT) ceramics prepared through solid-state reaction technique were investigated. X-ray powder diffraction study shows that bismuth evaporation and titanium excess result in the formation of the secondary nonperovskite phase and the deterioration of the sintering ability. The excessive bismuth and titanium cause the peak dielectric constant (Km) decrease and the temperature of the peak dielectric constant (Tm) shifts to lower temperature in the BCT-NBT systems. The appropriate bismuth oxide as a sintering aid leading to liquid phase sintering causes ceramics densification, increases the room temperature dielectric constant (K) and the remnant polarization (Pr) of BCT-NBT ceramics, and decreases the dielectric loss tangent and the coercive field (Ec) of the BCT-NBT ceramics. However, the excessive titanium causes a slight improvement of tangent and Ec. These results indicate that this chemical modification is necessary to synthesize BCT-NBT ceramics with better electrical properties in order to realize its practical applications.

备注：云斯宁

合写作者：XiaoliWang,JingShi,DelongXu

第一作者：云斯宁

论文类型：期刊论文

卷号：卷：485

期号：期：1-2

页面范围：页：610-615

是否译文：否

发表时间：2009-10-01